[tt] Cool Polymers: Toward the Microwave Oven Version of the Refrigerator

[Eugen Leitl]

http://www.sciam.com/article.cfm?id=cool-polymers&print=true

Scientific American Magazine -  October 30, 2008

Cool Polymers: Toward the Microwave Oven Version of the Refrigerator

Getting a bigger chill out of polymers that respond to electric fields

By Steven Ashley

Whether they sit in your kitchen or inside your personal computer,
refrigerators and other cooling devices are typically bulky, often noisy and
frequently power-hungry. A team at Pennsylvania State University recently
found that certain plastics cool off a significant amount—12 degrees
Celsius—when an applied electric field is removed. Should the technique
become feasible, the resulting solid-state coolers could efficiently and
quietly eliminate heat from, say, integrated-circuit boards, enabling
smaller, faster computers.

Engineers have long known of so-called electrocaloric substances that drop in
temperature when an external electric field is withdrawn, but the amount of
chilling either was too small at practical temperatures or occurred at too
high a temperature to be useful. Effective chip cooling, for instance,
requires reductions of at least 10 degrees C from typical operating
temperatures—about 85 degrees C, says G. Dan Hutcheson, chief executive
officer at VLSI Research, a microelectronics industry market research firm in
Santa Clara, Calif. Computers usually require heat sinks, radiators, fans,
heat pipes or even fluid-based heat pumps to extract the surplus degrees.

If successful, the new technology should be compact and at least 10 times
more energy-efficient than conventional cooling techniques, according to Penn
State electrical engineer Qiming Zhang, who led the team. The group found
that a micron-thick film of a polyvinylidene fluo­ride
co-polymer—polyvinylidene fluo­ride trifluoroethylene—heats up a dozen
degrees C when zapped with 120 volts at ambient temperatures as low as 55
degrees C. Such a rise constitutes an order of magnitude improvement over
other electrocaloric materials (mostly ceramics) at that temperature range.

Zhang, who in the past worked on plastic “artificial muscles” that alter
shape under electric fields, says that years ago he “started thinking about
melting ice into water, which is one of the most effective ways to cool
objects.” That effect is based on a phase change in which an ordered system
(solid ice) transforms in­to a disordered one (liquid water). In time, the
scientists identified several promising polymers in which an applied voltage
caused the atoms or molecules to align, thus creating greater order.

The electrocaloric materials, Zhang reports, consist of long molecular chains
with a positive electric charge on one end and negative on the other. These
dipolar chains, which can move around freely, are normally oriented randomly.
But “when you apply an electric field, the dipoles tend to spin around until
they align with the field,” he says. Thermodynamically speaking, this
molecular ordering lowers the system’s entropy, so the system compensates by
heating up as a consequence of energy conservation. When the field is
disengaged, the chains randomize and the polymer cools off. The rigid
microstructures of electrocaloric ceramics, in contrast, “can move only a
little bit,” Zhang notes, which accounts for their weak temperature response.
The polymers can also absorb seven times as much heat as the ceramics.

In an ideal solid-state refrigerator, a chilling cycle starts when contact
breaks between the polymer and the object that is being cooled, thermally
isolating the polymer. An applied electric field causes the temperature of
the polymer to rise. It is then placed into momentary thermal contact with a
heat sink, which absorbs any heat and entropy that the polymer has. The
polymer is next isolated from the heat sink; the electric field is then
lowered, which reduces the temperature of the polymer and enables it to cool
the target object once again.

A workable system could in particular prove a boon for the computer industry.
Silicon chips run hotter than is desirable for optimal performance, comments
Benson Inkley, a senior power/thermal engineer at Intel in Hillsboro, Ore.
Cooling with electrocaloric plastics offers intriguing possibilities, Inkley
states: “Imagine coating an entire circuit board with a layer of polymer, in
effect, forming a cooling blanket.”

But Zhang emphasizes that his polymer is not yet practical. One drawback is
that it requires 120 volts, much more than the few volts available in
portable devices.

He remains optimistic, though, and feels that the approach could scale up
beyond microelectronics. The development of larger refrigerators based on the
polymers depends on finding various other substances that exhibit the effect
at adjacent temperature ranges. That way the right combination could operate
as a “temperature cascade,” rejecting heat progressively. Says Zhang: “This
could be the first step in the development of an electric-field
refrigerator”—one with no bulky coils or noisy compressors. Someday chilling
a picnic cooler might mean flipping a switch rather than loading up on ice.

Chilling with Crystals

Other mobile dipolar molecules might offer solid-state cooling superior to
that of polyvinylidene fluoride co-polymers, Pennsylvania State University
engineer Qiming Zhang says. Especially promising are the molecules that form
images on flat-panel liquid-crystal displays (LCDs). Liquid crystals contain
rodlike dipoles that align with an electric field and revert to their
original arrangement when the field is removed. Zhang is as yet unsure if the
electric charges on the ends of the rods will respond strongly enough to
applied electric fields.

Note: This story was originally printed with the title, "Plastic Coolers".