[tt] New method 'self-assembles' metal atoms into porous nanostructures

[Brian Atkins]

http://www.nsf.gov/news/news_summ.jsp?cntn_id=111787&org=NSF

June 27, 2008

For 5,000 years the only way to shape metal has been by the "heat and beat" 
technique. Even with modern nanotechnology, metalworking involves carving metals 
with electron beams or etching them with acid.

Now Cornell researchers have developed a method to self-assemble metals into 
complex configurations with structural details about 100 times smaller than a 
bacterial cell by guiding metal particles into the desired form using soft polymers.

"I think this is ingenious work that takes the fundamental concepts of polymer 
science and applies them to make metals in a totally novel way," said Andrew 
Lovinger, the director of the Polymers Program at the National Science 
Foundation. "In so doing, it opens the door to all kinds of new possibilities."

Applications include making more efficient and cheaper catalysts for fuel cells 
and industrial processes, and creating "plasmonic" surface structures capable of 
carrying more information across microchips than conventional wires do.

"The polymer community has tried to do this for almost 20 years," said Uli 
Wiesner, Cornell professor of materials science and engineering, who reports on 
the new method in the June 27, 2008, issue of the journal Science. "But metals 
have a tendency to cluster into uncontrolled structures."

Wiesner's research team has now developed a method to overcome this globby 
inclination of metals. First, metal nanoparticles measuring about 2 nanometers 
(nm) or 10-20 atoms in diameter, are coated with an organic material known as a 
ligand. The ligands form thin jackets around the metal atoms, changing their 
surface chemistry. Keeping the ligand jackets thinly tailored is a key factor 
that permits the volume of metal in the final structure to be large enough to 
hold its shape when the organic materials are eventually removed.

The jacketed metal atoms are then put in a solution containing block 
co-polymers, a kind of nano-scaffolding material. The innovative use of the 
ligands allows for the metal nanoparticles to be dissolved--even at high 
concentrations--in such a solution. A block co-polymer is made up of two 
different long chains, or blocks, of molecules linked together to form a 
predictable pattern. In the experiment, depicted in the illustration at right, 
ligand-coated platinum nanoparticles (shown as blue and gray balls) are nestled 
amongst the block co-polymers (shown as blue and green strands).

After the ligand-coated nanoparticles and polymers assemble in regular patterns, 
the material is heated to high temperatures in the absence of air to convert the 
polymers to a carbon scaffold. The scaffold is then allowed to cool. Because the 
metal nanoparticles have a very low melting point, without the carbon scaffold 
they would stubbornly fuse together in an uncontrolled fashion. Using this 
process, the carbon scaffold can be etched away with an acid, leaving behind a 
structured solid metal.

The Cornell group used the new method to create a platinum structure (see 
illustration above) with uniform hexagonal pores, each on the order of 10 nm 
across--a much larger diameter than previous attempts have been able to produce. 
Platinum is, so far, the best available catalyst for fuel cells, and a spacious 
pore structure allows fuel to flow through and react over a larger surface area.

"It opens a completely novel playground because no one has been able to 
structure metals in bulk ways using polymers," Wiesner explained. "In principle, 
if you can do it with one metal you can do it with others or even mixtures of 
metals."

In addition to making porous materials for catalysis, the researchers said, the 
technique could be used to create finely structured metals on surfaces, a key to 
transform the field of plasmonics, which studies the interactions among metal 
surfaces, light, and density waves of electrons, known as plasmons. Currently, 
researchers are investigating the use of plasmons to transmit more information 
across metal wires in microchips and to improve optics applications, like 
lasers, displays, and lenses.

The research team was led by Uli Wiesner at Cornell University and included 
Francis DiSalvo, the J.A. Newman Professor of Chemistry and Chemical Biology, 
and Sol Gruner, the John L. Wetherill Professor of Physics, both at Cornell, and 
other undergraduate and graduate students.

The research was funded by the National Science Foundation and the Cornell Fuel 
Cell Institute.

-NSF-

-- 
Brian Atkins
Singularity Institute for Artificial Intelligence
http://www.singinst.org/