[tt] advanced nanotechnology - 6 new articles

Eugen Leitl <eugen at leitl.org> on Wed Jan 9 09:25:15 UTC 2008

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Subject: advanced nanotechnology - 6 new articles
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"[2]advanced nanotechnology" - 6 new articles

    1. [3]Silicon electronics providing early versions of nanomedicine
       expectations
    2. [4]Four behaviors add 14 extra years of life
    3. [5]Mathematical model for droplets in an electric field
    4. [6]Carbon nanotubes on plastic 312 megahertz instead of kilohertz
       for current plastic circuits
    5. [7]Reviewing the specifics of the MIT 50% power uprate plans
    6. [8]Another new take on solar power and thermoelectric conversion
    7. [9]More Recent Articles
    8. [10]Search advanced nanotechnology

[11]Silicon electronics providing early versions of nanomedicine
expectations

   [12]Nanowerk has a review of nanomedicine. In particular the EU view
   from the 7th FWP which refers to the European Union's Seventh
   Framework Program
   [2178776887_564284b000_o.jpg]
   this shows the many different aspects and capabilities related to
   nanomedicine
   The expected change in the understanding of disease that they discuss
   in this quote:

     Future nanomedical diagnostics with an ultimate level of
     sensitivity will enable doctors to discover the slightest
     abnormality in our bodies - raising the question if and what
     clinical relevance such information will have.
     "Diagnostic nanotechnologies eventually will provide the ability to
     detect and characterize individual cells, subtle molecular changes
     in DNA, or even minor changes in blood chemistry - scenarios that
     will likely cause pause and reconsideration of what it means to be
     a 'healthy person' versus a 'person who has a disease'" says Bawa.
     "In a 'nanoworld,' we might have to reconsider how to diagnose
     someone who has, say, cancer. Is the presence of a genetic mutation
     known to have a predisposition for causing cancer in a single cell
     a diagnosis? Or is it simply a risk factor? How many cells from the
     body must be of a cancerous nature for it to be defined as cancer?
     1? 50? 1000?"
     Once diagnostic technologies have reached this stage it will
     require reconceptualizing understanding of disease

   [13]Is already arriving with labs on a chip that can accurately count
   cancer cells and find 99.1% of metastatic cancer in the blood.
   [14]Silicon biosensors are being implanted into the body with a gel to
   prevent rejection.
   [15]There are bloodstream robots that are millimeter sized or smaller
   from Korea and Japan and [16]and Israel.
   [minuscule_submarine_robot.jpg]
   Israel bloodstream robot
   With the rejection suppression gel, rice grain size or larger
   computers could be placed into the body which would be an earlier
   cruder but possibly very functional version of what nanomedicine could
   accomplish. MEMS and NEMS will get very good over the next 5-10 years
   and the conservative expectations that we will need to wait for full
   blown nanotechnology for what are considered nanomedicine applications
   are wrong. Molecular nanotechnology will make what we can place into
   the body a millions times higher performance or more. However, even
   advanced silicon and polymer and pre-molecular nanotechnology will
   provide capabilities far beyond what those who ridicule "submarines in
   the body" expect.
   Do not underestimate clever and creative use of existing and near term
   technology. It can deliver what some people think we need to wait for
   full blown molecular nanotechnology to get. It also means clever use
   of molecular nanotechnology will blow away all the unimaginitive
   scenarios.
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   expectations'

[30]Four behaviors add 14 extra years of life

   [31]If you do not smoking; exercise; moderate alcohol intake; and
   eating five servings of fruit and vegetables a day then you will live
   on average an additional fourteen years compared with people who adopt
   none of these behaviours.
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[45]Mathematical model for droplets in an electric field

   [46]Mathematical model created for formation of droplets in an
   electric field. Further progress in extending the model for variations
   under more conditions will be key in formalizing the process of
   improving inkjet printers Inkjet printing technology is the basis of
   printable electronics and many rapid prototyping fabrication systems.
   An accurate computational model will allow for rapid optimization of
   inkjet based systems.
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[60]Carbon nanotubes on plastic 312 megahertz instead of kilohertz for
current plastic circuits

   [61]Scientists from the University of Massachusetts Lowell and Brewer
   Science, Inc. have used carbon nanotubes as the basis for a high-speed
   (312 megahertz) thin-film transistors printed onto sheets of flexible
   plastic. Their method may allow large-area electronic circuits to be
   printed onto almost any flexible substrate at low cost and in mass
   quantities. (Most Intel and AMD processors are in the 2 to 3 Gigahertz
   range)
   [62]The Pentium II (mid-97 to 1999) had processor speeds of 233-450
   Mhz The new carbon nanotubes of plastic have processor speeds in that
   range and can be printed in large sheets in process taht is similar to
   inkjet printing.

     Applications for these flexible electronics include electronic
     paper, RFID (radio frequency identification) tags to track goods
     and people, and "smart skins," which are materials and coatings
     containing electronic circuitry that can indicate changes in
     temperature or pressure, such as on aircraft or other objects.
     Our electronic-grade solutions contain ultrapure carbon nanotubes
     without using any surfactant. Our printed transistor's carrier
     mobility is much higher than similar devices developed by other
     groups, it exhibits a speed of 312 megahertz, and can carry a large
     current.
     As part of the printed-electronics effort, carbon nanotubes have
     been investigated as a medium for high-speed transistors, with very
     promising results. But one method of depositing the nanotubes onto
     the plastic, "growing" them with heat, requires very high
     temperatures, typically around 900°C, which is a major obstacle for
     fabricating electronic devices.
     Brewer Science, Inc. developed an electronic-grade carbon-nanotube
     solution. The researchers deposited a tiny droplet of the solution
     onto a plastic transparency film at room temperature using a
     syringe, a method similar to ink-jet printing.

   FURTHER READING
   [63]Other printable electronics.
   [64]Kovio's inkjet printable electronics has electron mobility of ~80
   cm2/(V·s).
   Many companies and R&D labs have been aiming at getting the electron
   mobility--expressed in units of cm2/(V·s)--of organics semiconductors
   up to the 0.5-1.0 range of amorphous-silicon TFTs.
   Previous reports have shown that C60 can yield mobility values as high
   as six square centimeters per volt-second (6 cm2/V/s). However, that
   record was achieved using a hot-wall epitaxy process requiring
   processing temperatures of 250 degrees Celsius - too hot for most
   flexible plastic substrates.
   Though the transistors produced by Kippelen's research team display
   slightly lower electron mobility - 2.7 to 5 cm2/V/s - they can be
   produced at room temperature.
   [65]Graphene has high potential. Electron mobility in graphene is
   200,000 cm2/Vs and more than 100 times higher than for silicon -
   researchers believe graphene has the potential to improve upon the
   capabilities of current semiconductors and open up exciting new
   possibilities. These include ultra-high frequency detectors required
   for full-body security scanners, which would make people transparent
   by operating at terahertz (THz) frequencies. However, most estimate it
   will be 20 years before that full potential will be realized.
   [66]Fuhrer's group measured 100,000-cm2/volt-second mobility at room
   temperature for the nanotube structures. That's about 70 times the
   1,500-cm2/V-s mobility of standard silicon chips and 10 times the
   10,000 cm2/V-s achievable by silicon's mobility leaders, discrete
   high-electron-mobility transistors (HEMTs). The mobility record set by
   InSb in 1955 was 77,000.
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   kilohertz for current plastic circuits'

[80]Reviewing the specifics of the MIT 50% power uprate plans

   MIT/Westinghouse are developing annular fuel and looking at
   nanoparticles to improve the thermal properties of water for nuclear
   plants. The peak hotspot operating temperature can go down while
   efficiency is increased. I usually mention this technology as
   something which would make a huge difference in nuclear power
   generation. I am reviewing the work and updating with some recent
   journal references.
   [2166766541_ca2fcd0f03.jpg?v=0]
   Solar power is 1/30th of 1%. Boosting nuclear power by 50% would be
   like doubling hydroelectric and all renewable power. It would be 300
   times all of the solar power in the USA in 2006.
   The fuel is especially well suited for pressurized water reactors,
   which make up 60% of the world's 443 reactors. Hejzlar says that
   utilities in the U.S., Japan, and South Korea have expressed interest
   in his design.
   The annular fuel would boost power by 50%.
   The nanoparticles in fluid would boost power by 20% for existing
   reactors and 40% for new reactors.
   The cross shaped spiral design would boost boiler water reactors by
   30%.
   [81]The MIT fuel is thin walled donuts with pellets inside and using
   nanoparticles in the fluid.
   [2179444138_3d8e19027a.jpg?v=0]
   The tubes with uranium particles

     The new design also helps diminish the chance of meltdown by
     slashing the temperature at which reactors must be operated, and it
     renders the spent fuel more proliferation-resistant.
     Reactors that use the new fuel can operate at 700 °C--less than
     half of the 1800 °C required for conventional fuel. This takes the
     reactor temperature much farther away from the 2840 ° C at which
     meltdowns can occur. The temperature is so much lower because the
     doughnut shape enables heat to flow in two directions and the
     surface-area-to-volume ratio is about 60% higher, Hejzlar explains.
     "A traditional fuel rod looks like a pencil, with the fuel pellets
     inside the tube and water flow on the outside of the tube. Annular
     fuel is like a thick-walled stra... or a very thin-walled
     doughnut," explains Edward Lahoda, a nuclear engineer at
     Westinghouse Corp., a major manufacturer of pressurized water
     reactors.
     The new fuel is much more complex to manufacture than conventional
     cylindrical pellets. But when Westinghouse made a test run of
     producing the annular pellets, they achieved a "very good yield" of
     greater than 95%, Lahoda says. "Manufacturing is not a trivial
     issue," he stresses. "If you can't make them in millions of pellets
     and load them into hundreds of thousands of rods, the concept is
     useless."

   [82]In a three-year project completed recently [2006] for the U.S.
   Department of Energy, Hejzlar and Kazimi teamed up with Westinghouse
   and other companies to look at how to make a fuel for one kind of
   reactor, the pressurized water reactor (PWR), 30 percent more
   efficient while maintaining or improving safety magins. [the pilot
   study]
   They changed the shape of the fuel from solid cylinders to hollow
   tubes. This added surface area that allows water to flow inside and
   outside the pellets, increasing heat transfer.
   The new fuel turned out even better than Hejzlar dared hope. It proved
   to be easy to manufacture and capable of boosting the power output of
   PWR plants by 50 percent.
   The next step is to commercialize the fuel concept, which will include
   testing a limited number of rods filled with the new pellets in an
   operating reactor and examining the results to ensure the safety and
   performance of the new fuel.
   [83]PWR Transition to a Higher Power Core Using Annular Fuel

     The internally and externally cooled annular fuel is a new type of
     fuel for PWRs that enables an increase in core power density by 50%
     within the same or better safety margins as traditional solid fuel.
     Each annular fuel assembly of the same size dimensions as solid
     fuel has 160 annular fuel rods arranged in a 13x13 array. Even at
     the much higher power density, the fuel exhibits substantially
     lower temperatures and a Minimum Departure From Nucleate Boiling
     (MDNBR) margin comparable to that of traditional solid fuel at
     nominal (100%) power. The major motivation for such an uprate is
     reduction of electricity generation cost. Indeed, the capital cost
     per kWh(e) of a new reactor would be smaller than the standard
     construction of a new
     reactor with solid fuel.
     This option implies running a core with a mixture of both annular
     and solid fuel assemblies. In order to prove the technical
     feasibility of such an option, the thermal-hydraulics of this mixed
     core is investigated and the MDNBR is found to be either unaffected
     or improved. Consequently, a neutronic model is developed to verify
     and validate the neutronic feasibility of the transition from solid
     to annular fuel. This involvements assessment of the peaking
     factors and capability to provide control poisons within allowable
     concentrations The overall conclusion of this work is that annular
     fuel is a very promising option for existing reactors to increase
     their power by 50%, as it enables a significant uprate with an
     attractive return on investment. We show that, by a smart
     management of the transition, an internal return investment of
     about 22-27% can be achieved. 

   Nanoparticle Spiked water
   [2179444132_802e56399a_o.jpg]
   Nanofluid can boost PWR power by 20% for existing reactors and 40% for
   new reactors

     Jacopo Buongiorno, assistant professor of nuclear science and
     engineering, has come up with a way to change water's thermal
     properties. This change may contribute to plants' safety while
     boosting their power density, or the amount of energy they can pump
     out.
     The efficiency of PWRs and BWRs is limited to around 33 percent,
     because water can be heated to only a certain temperature and only
     a certain amount of heat can be taken out of water. If that limit
     were pushed higher, more heat could be extracted, and the plant
     would generate more energy at a lower cost.
     His laboratory works on nanofluids -- base fluids such as water
     interspersed with tiny particles of oxides and metals only
     billionths of a meter in diameter. Buongiorno's nano-spiked water,
     transparent but somewhat murky, can remove up to two times more
     heat than ordinary water, making it an ideal substance for nuclear
     plants.
     Nanoparticles in the water that cools the outer surface of the
     vessel raise the amount of heat that can be drawn away from the
     core, making the plant less susceptible to the negative
     repercussions of a possible meltdown.
     The key issue to be resolved before nanofluids can be used in
     nuclear plants, Buongiorno said, is the stability of the
     nanoparticles, which could agglomerate and settle quickly if
     appropriate chemical and thermal conditions are not carefully
     maintained.

   [2179444136_1a55228319.jpg?v=0]
   Silicon cladding would be tougher and safer than zirconium alloy on
   fuel rods
   [84]MIT work to improve boiler water reactor performance and safety
   [2179459812_52d6b63497_o.jpg]
   FURTHER READING
   [85]Agressive and new technology nuclear power uprates, new
   thermoelectronics and a climate change bill could boost nuclear power
   by 675% by 2030
   [86]Thermoelectrics being developed by the DOE freedomcar project can
   capture 50+% of waste heat for electricity
   [87]The EIA analysis of the effect of a climate change bill passing
   Two to three times more nuclear power from increased nuclear plant
   build. It does not consider the MIT work or the thermoelectrics.
   On the changes of a climate change bill passing:
   A bill is already in front of the Senate and [88]>passed the senate
   committee.
   Clinton and Obama would support a stronger climate change bill.
   McCain co-authored the one analyzed by the EIA
   The other republicans support nuclear power.
   Michael Bloomberg has asked for a carbon tax which would have an even
   stronger effect than the climate change bill.
   [89]A lot of other work on improving nuclear reactor efficiency and
   performance.
   [90]Annular fuel special issue of American Nuclear Society 2007
   [91]Page 5 of westinghouse 28 page 2004 worldview mentions the MIT 50%
   power uprate work
   [92]MIT fission research homepage
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[106]Another new take on solar power and thermoelectric conversion

   [107]Another potentially more efficient way to convert heat into
   electricity, from x-NASA super soaker inventor.

     Here's how it works: One MEA stack is coupled to a high-
     temperature heat source (such as solar heat concentrated by
     mirrors), and the other to a low-temperature heat sink (ambient
     air). The low-temperature stack acts as the compressor stage while
     the high-temperature stack functions as the power stage. Once the
     cycle is started by the electrical jolt, the resulting pressure
     differential produces voltage across each of the MEA stacks. The
     higher voltage at the high-temperature stack forces the
     low-temperature stack to pump hydrogen from low pressure to high
     pressure, maintaining the pressure differential. Meanwhile hydrogen
     passing through the high-temperature stack generates power.
     "It's like a conventional heat engine," explains Paul Werbos,
     program director at the National Science Foundation, which has
     provided funding for JTEC. "It still uses temperature differences
     to create pressure gradients. Only instead of using those pressure
     gradients to move an axle or wheel, he's using them to force ions
     through a membrane. It's a totally new way of generating
     electricity from heat."

   [108][advancednano?i=misKLsD] [109][advancednano?i=3fHag9D]
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----- End forwarded message -----
-- 
Eugen* Leitl <a href="http://leitl.org">leitl</a> http://leitl.org
______________________________________________________________
ICBM: 48.07100, 11.36820 http://www.ativel.com http://postbiota.org
8B29F6BE: 099D 78BA 2FD3 B014 B08A  7779 75B0 2443 8B29 F6BE

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