[tt] Next Big Future - 4 new articles

Eugen Leitl <eugen at leitl.org> on Tue Aug 19 17:15:05 UTC 2008

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"[2]Next Big Future" - 4 new articles

    1. [3]Oil has streak of positive news
    2. [4]Competitors for kite generated wind power
    3. [5]Highest 50 nanometer resolution X-ray holograms
    4. [6]Thermoelectrics and refrigerators
    5. [7]More Recent Articles
    6. [8]Search Next Big Future

[9]Oil has streak of positive news

   [10]Oil supply is running on a streak of positive news after a lot of
   negative news pushed oil prices up.
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     Saudi Arabia apparently hit its target of 9.7 million barrels a day
     in July. There is a steady recovery in oil production from the Gulf
     of Mexico, where Hurricane Katrina demolished rigs and set back
     plans by months and in some cases years. BP's Thunder Horse
     platform, which was left a listing hulk by Katrina, finally began
     production last month and should be pumping 250,000 barrels a day
     by the end of next year. Thunder Horse is believed to be the
     largest oil find ever in the Gulf of Mexico. As oil companies
     return to their pre-Katrina schedules, Littell says, "we should see
     one or two of these (new Gulf of Mexico projects) every quarter
     through 2009."

   [17]Crude oil fell to a 13-week low amid speculation that Tropical
   Storm Edouard will miss most offshore oil facilities as it approaches
   the coast of Texas.
   FURTHER READING
   [18]Oil mega projects for 2008 from wikipedia

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[36]Competitors for kite generated wind power

   [37]Scientists from Delft University of Technology in the Netherlands
   harnessed energy from the wind by flying a 10-sq metre kite tethered
   to a generator, producing 10 kilowatts of power.
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   An Italian company, Kitegen, has come up with a theoretical design for
   a system that could generate a gigawatt, as much power as a standard
   coal-fired power station. Its idea involves flying 12 sets of lines
   with four 500-sq metre kites on each. Kitegen has been covered several
   times by this site.
   [44]Researchers have plans to test a 50kW version of their invention,
   called Laddermill, eventually building up to a proposed version with
   multiple kites that they claim could generate 100 megawatts, enough
   for 100,000 homes.
   Furey has worked out that flying kites in a figure of eight pattern
   means the air flowing over them travels even faster than the ambient
   wind speed. When a kite needs to be reeled in, it is angled so that it
   falls out of the sky like a glider, without the need for much power.
   Ockels's system uses these flying patterns to maximise the power the
   kites can generate. He is also looking at extending his basic
   prototype to use multiple kites that yo-yo: when one goes up, another
   goes down. Ockels estimates that kites could generate power at less
   than 4p per kilowatt-hour.
   Google.org, the philanthropic arm of the Californian web-search
   company, invested $10m (about £5m) last year in a US kite company
   called [45]Makani Power Inc.
   The aim of both teams is to tap into high-altitude wind, which is an
   energy source that is more abundant and reliable than the ground-level
   wind on which normal turbines depend.
   Ken Caldeira, a climate scientist at Stanford University's Carnegie
   Institution, has estimated that the total energy contained in wind is
   100 times the amount needed by everyone on the planet. But most of
   this energy is at high altitude.

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[63]Highest 50 nanometer resolution X-ray holograms

   Top: the ALS beamline 9.0.1 experiment used a uniformly redundant
   array (URA) 30 nanometers thick with scattering elements 44 nanometers
   square (left). At right is the lithograph of Da Vinci's Vitruvian Man.
   The scale bar is two micrometers long. Bottom: the FLASH experiment
   used a URA with 162 pinholes, next to a Spiroplasma bacterium. The
   150-nanometer diameter pinholes in the URA limited resolution, but
   computer processing improved image resolution to 75 nanometers. The
   scale bar is four micrometers long.
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   [70]The pinhole camera, a technique known since ancient times, has
   inspired a futuristic technology for lensless, three-dimensional
   imaging. Working at both the Advanced Light Source (ALS) at the U.S.
   Department of Energy's Lawrence Berkeley National Laboratory, and at
   FLASH, the free-electron laser in Hamburg, Germany, an international
   group of scientists has produced two of the brightest, sharpest x-ray
   holograms of microscopic objects ever made, thousands of times more
   efficiently than previous x-ray-holographic methods.
   The x-ray hologram made at ALS beamline 9.0.1 was of Leonardo da
   Vinci's famous drawing, "Vitruvian Man," a lithographic reproduction
   less than two micrometers (millionths of a meter, or microns) square,
   etched with an electron-beam nanowriter. The hologram required a
   five-second exposure and had a resolution of 50 nanometers (billionths
   of a meter).
   The other hologram, made at FLASH, was of a single bacterium,
   Spiroplasma milliferum, made at 150-nanometer resolution and
   computer-refined to 75 nanometers, but requiring an exposure to the
   beam of just 15 femtoseconds (quadrillionths of a second).
   The values for these two holograms are among the best ever reported
   for micron-sized objects. With already established technologies,
   resolutions obtained by these methods could be pushed to only a few
   nanometers, or, using computer refinement, even better.
   FURTHER READING
   [71]The research paper at Nature Photonics 
   Massively parallel X-ray holography
   Stefano Marchesini, Sébastien Boutet, Anne E. Sakdinawat, Michael J.
   Bogan1, Sas carona Bajt1, Anton Barty1, Henry N. Chapman1, Matthias
   Frank1, Stefan P. Hau-Riege1, Abraham Szöke1, Congwu Cui, David A.
   Shapiro, Malcolm R. Howells, John C. H. Spence, Joshua W. Shaevitz,
   Joanna Y. Lee, Janos Hajdu & Marvin M. Seibert
   Advances in the development of free-electron lasers offer the
   realistic prospect of nanoscale imaging on the timescale of atomic
   motions. We identify X-ray Fourier-transform holography as a promising
   but, so far, inefficient scheme to do this. We show that a uniformly
   redundant array4 placed next to the sample, multiplies the efficiency
   of X-ray Fourier transform holography by more than three orders of
   magnitude, approaching that of a perfect lens, and provides
   holographic images with both amplitude- and phase-contrast
   information. The experiments reported here demonstrate this concept by
   imaging a nano-fabricated object at a synchrotron source, and a
   bacterial cell with a soft-X-ray free-electron laser, where
   illumination by a single 15-fs pulse was successfully used in
   producing the holographic image. As X-ray lasers move to shorter
   wavelengths we expect to obtain higher spatial resolution ultrafast
   movies of transient states of matter.

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[89]Thermoelectrics and refrigerators

   [90]Members of the Quantum Simulations Group at Lawrence Livermore
   National Labs provide an extensive discussion of how thermoelectrics
   can replace freon based refrigerators when inexpensive thermoelectric
   materials reach a ZT of 3.
   The Livermore group has begun working on simulations [modeling
   material processes using quantum molecular dynamics methods] for a
   diverse group of technological applications. For example, nanoscale
   materials could improve cooling technologies in military equipment and
   reduce the size of gamma radiation detectors being developed for
   homeland security.
   Thermoelectric materials convert heat into electricity and vice versa.
   They have no moving parts and release no pollutants into the
   environment. A few niche markets have used them for decades to cool
   electrical parts or generate power. Researchers have considered using
   thermoelectric-based refrigerators to replace current heat-pump-based
   refrigerators that compress and expand a refrigerant such as Freon.

     Canted nanowires grown in the [001] direction can achieve a ZT of
     3.5 but require considerable doping with either phosphorus or
     boron. "I doubt that the wires could be doped strongly enough for
     this surface to work," says Vo. "Wires grown in the [011] direction
     will probably be the best compromise."
     Although the low effective mass of silicon increases electrical
     conductivity, it also contributes to a high thermal conductivity.
     Thermal conductivity must be low for a thermoelectric material to
     be efficient. One solution is to change the material used for the
     wires. Vo's simulations indicate that a SiGe combination will
     reduce lattice thermal conductivity by as much as five times
     without affecting electrical conductivity.

   From the [91]Air Conditioning and Refrigeration Technology Institute:
   [92]The final report on thermoelectric technology assessment of the
   ACRT institure

     The energy conversion efficiency, or Coefficient of Performance
     (COP) of thermoelectric cooling devices, is determined by
     thermoelectric figure-of-merit, commonly denoted by ZT. The highest
     ZT to date is reported in Bi2Te3/Sb2Te3 and PbSeTe/PbTe
     superlattice thin films. Coolers based on such materials typically
     have a COP of ~2, which is lower than the COP of 3-4 vapor
     compression refrigerators. However, there is no known theoretical
     impediment to significant increases in thermoelectric energy
     conversion efficiency, and given a breakthrough in materials,
     thermoelectric technology might offer the possibility of a safe,
     efficient, and affordable alternative to fluorocarbon compression
     equipments.
     The use of thermoelectric devices and systems has been limited by
     their relative low energy conversion efficiency. Present commercial
     thermoelectric devices operate at about 10% of Carnot efficiency,
     whereas the efficiency of a compressor-based refrigerator increases
     with size: a kitchen refrigerator operates at about 30% of Carnot
     efficiency and the largest air conditioners for big buildings
     operate near 90%.
     Today's thermoelectric devices are particularly useful when the
     efficiency is a less important issue than small size, low weight,
     or high reliability. For example, thermoelectric devices are suited
     for situations where the heat load is small (say, <25W) or the
     temperature lift is small (say <10C) or the variation of the heat
     load is large (e.g., train passenger cabin). It is important to
     note that the COP of thermoelectric coolers increases significantly
     with decreasing the temperature lift.
     o Instead of utilizing a full-fledged thermoelectric cooling
     system, it is possible to use a thermoelectric heat pump to improve
     the performance of an existing vapor compression system, so called
     "hybrid system." For example, a hybrid vapor compression -
     thermoelectric cooler systems could use thermoelectric heat pumps
     to enhance the outlet subcooling of a condenser, in which
     thermoelectric heat pumps operate at small DT and high COP.
     Theoretical analysis predicted the cooling capacity and COP of the
     hybrid system could be significantly improved.
     Thermoelectric heat pumps could operate at very high COP (possibly
     COP>6)under the condition of small temperature lift. They would
     provide a high COP boost to conventional refrigerating systems.
     The thermoelectric subcooler is modeled as additional component
     that provides a given temperature lift. The simulation results are
     shown below
     The important findings from the studies are listed below:
     o A theoretical maximum improvement of 16.2% in COP can be
     achieved. The
     corresponding increase in cooling capacity is about 20%.
     o A theoretical maximum improvement of 35% in capacity can be
     achieved,
     without change in COP.
     o No increase in the size of the heat exchangers in the system.
     o The economic aspects of coupling a thermoelectric device with a
     conventional
     vapor compression system remain to be investigated.
     o High Reliability: Thermoelectric coolers possess high
     reliability. Depending on
     the conditions of application, the lifetime of thermoelectric
     coolers is in the range
     of 100,000 to 200,000 hours

   FURTHER READING
   [93]The old thermoelectric coolers from 1996

     Thermoelectric coolers are solid state heat pumps used in
     applications where temperature stabilization, temperature cycling,
     or cooling below ambient are required. There are many products
     using thermoelectric coolers, including CCD cameras (charge coupled
     device), laser diodes, microprocessors, blood analyzers and
     portable picnic coolers.

   [94]12 questions about thermoelectric cooling
   
     Let's look conceptually at a typical thermoelectric system designed
     to cool air in an enclosure (e.g., picnic box, equipment enclosure,
     etc.); this is probably the most common type of TE application.
     Here the challenge is to 'gather' heat from the inside of the box,
     pump it to a heat exchanger on the outside of the box, and release
     the collected heat into the ambient air. Usually, this is done by
     employing two heat sink/fan combinations in conjunction with one or
     more Peltier devices. The smaller of the heat sinks is used on the
     inside of the enclosure; cooled to a temperature below that of the
     air in the box, the sink picks up heat as the air circulates
     between the fins. In the simplest case, the Peltier device is
     mounted between this 'cold side' sink and a larger sink on the 'hot
     side' of the system. As direct current passes through the
     thermoelectric device, it actively pumps heat from the cold side
     sink to the one on the hot side. The fan on the hot side then
     circulates ambient air between the sink's fins to absorb some of
     the collected heat. Note that the heat dissipated on the hot side
     not only includes what is pumped from the box, but also the heat
     produced within the Peltier device itself (V x I).
     Let's look at this in terms of real numbers. Imagine that we have
     to pump 25 watts from a box to bring its temperature to 3°C
     (37.4°F) from a 20°C (68°F) ambient. To accomplish this, we might
     well have to take the temperature of the cold side sink down to 0°
     C (32°F). Using a Peltier device which draws 4.1 amps at 10.4 V,
     the hot side of the system will have to dissipate the 25 watts from
     the thermal load plus the 42.6 watts it takes to power the TE
     module (for a total of 67.6 watts). Employing a hot side sink and
     fan with an effective thermal resistance of 0.148 C°/W (0.266F°/W),
     the temperature of the hot side sink will rise approximately 10°C
     (18°F) above ambient. It should be noted that, to achieve the 17° C
     drop (30.6°F) between the box temperature and ambient, we had to
     create a 30° C (54°F) temperature difference across the Peltier
     device.

   [95]More research papers from the Air Conditioning and Refrigeration
   Technology Institute.
   [96]More research projects of the ACRT institute.
   Existing commercial thermoelectric refrigerating cooler [many other
   high end applications listed in the ACRT thermoelectric assessment
   report:
   [97]The Igloo Kool Mate 56-Quart Thermoelectric Cooler sold at Walmart
   for $119.73
   - Plugs into 12V utility outlet in your boat or car
   - 56-quart (1.9 cubic feet) capacity holds up to 72 twelve-ounce cans
   - Cools to down to 44-degrees F below outside temperature
   [98]This site has already reported that there is about a billion
   dollars in research from the US military and the Department of Energy
   on thermoelectrics.
   Replacing Freon in AC and refrigerators would be a big part of
   reducing greenhouse gases. Freon refrigerant gas was banned from
   vehicular air conditioning systems In the mid 1990's to prevent Ozone
   Layer depletion. R134-a refrigerant gas was universally adopted as the
   replacement However R134-a has 1,300 times* the global warming
   potential of CO2 The European Union is prohibiting use of R134-a in
   cars for
   o New models in 2011
   o All new cars in 2017
   [1486192040_9b770a2353.jpg?v=0]
   The research goal is included on page 35 of the 55 page slide deck
   presentation by [99]Vehicular Thermoelectrics Applications Overview
   ,John W. Fairbanks, Technology Development Manager-Thermoelectrics,
   U.S. Department of Energy - Washington, DC, Presented at the DEER
   2007, Detroit, Michigan August 15, 2007

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----- End forwarded message -----
-- 
Eugen* Leitl <a href="http://leitl.org">leitl</a> http://leitl.org
______________________________________________________________
ICBM: 48.07100, 11.36820 http://www.ativel.com http://postbiota.org
8B29F6BE: 099D 78BA 2FD3 B014 B08A  7779 75B0 2443 8B29 F6BE

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